Effect of Temperature on Co-Pyrolysis of Palm Kernel Shell and Plastic Waste under Natural Catalysts

Thoharudin Thoharudin

Abstract


Pyrolysis is a potential process for converting solid waste, such as biomass and plastic waste, into useful fuels and chemicals in liquid, solid, and gas forms. The pyrolysis temperature is a critical factor that influences the amount and quality of the product. Furthermore, the use of natural catalysts such as calcium oxide and natural zeolite affects the pyrolysis products. Thus, the purpose of this study is to evaluate the influence of temperature on the amount and quality of pyrolysis products, especially pyrolysis oil, using calcium oxide and natural zeolite catalysts. Pyrolysis was carried out in a stainless steel fixed-bed reactor. The temperature was kept at 400, 450, and 500 oC. The pyrolysis vapor was cooled with a water-jacket condenser, and the oil and wax were collected in an oil chamber. This study found that the pyrolysis temperatures had a substantial impact on the pyrolysis product yields. Furthermore, they influenced the density, viscosity, acidity, heating value, and chemical composition of the liquid product discussed in this study.

References


Y. Wang, L. Huang, T. Zhang, and Q. Wang, “Hydrogen-rich syngas production from biomass pyrolysis and catalytic reforming using biochar-based catalysts,” Fuel, vol. 313, p. 123006, 2022, doi: 10.1016/j.fuel.2021.123006.

L. Maulinda et al., “Effects of temperature and times on the product distribution of bio-oils derived from Typha latifolia pyrolysis as renewable energy,” Results Eng., vol. 18, p. 101163, 2023, doi: 10.1016/j.rineng.2023.101163.

S. Acharya, D. Sen Gupta, and N. Kishore, “In-situ catalytic hydro-liquefaction of Delonix regia lignocellulosic biomass waste in hydrogen-donor solvent,” Results Eng., vol. 16, p. 100734, 2022, doi: 10.1016/j.rineng.2022.100734.

A. W. Go, A. T. Conag, R. M. B. Igdon, A. S. Toledo, and J. S. Malila, “Potentials of agricultural and agro-industrial crop residues for the displacement of fossil fuels: A Philippine context,” Energy Strateg. Rev., vol. 23, pp. 100–113, 2019, doi: 10.1016/j.esr.2018.12.010.

I. P. Okokpujie et al., “Modelling and optimisation of intermediate pyrolysis synthesis of bio-oil production from palm kernel shell,” Clean. Eng. Technol., vol. 16, p. 100672, 2023, doi: 10.1016/j.clet.2023.100672.

S. E. Hosseini, M. A. Wahid, and A. Ganjehkaviri, “An overview of renewable hydrogen production from thermochemical process of oil palm solid waste in Malaysia,” Energy Convers. Manag., vol. 94, pp. 415–429, 2015, doi: 10.1016/j.enconman.2015.02.012.

R. Nabila et al., “Oil palm biomass in Indonesia: Thermochemical upgrading and its utilization,” Renew. Sustain. Energy Rev., vol. 176, p. 113193, 2023, doi: 10.1016/j.rser.2023.113193.

Thoharudin, Y.-S. Chen, and S.-S. Hsiau, “Numerical studies on fast pyrolysis of palm kernel shell in a fluidized bed reactor,” 2020, doi: 10.1088/1757-899X/874/1/012033.

Thoharudin, M. Nadjib, T. H. Agung Santosa, Juliansyah, A. Zuniardi, and R. Shihabudin, “Properties of co-pyrolysed palm kernel shell and plastic grocery bag with CaO as catalyst,” in IOP Conference Series: Earth and Environmental Science, 2018, vol. 209, no. 1, doi: 10.1088/1755-1315/209/1/012041.

J. Pan, H. Jiang, T. Qing, J. Zhang, and K. Tian, “Transformation and kinetics of chlorine-containing products during pyrolysis of plastic wastes,” Chemosphere, vol. 284, p. 131348, 2021, doi: 10.1016/j.chemosphere.2021.131348.

M. Liu et al., “A benefit evaluation for recycling medical plastic waste in China based on material flow analysis and life cycle assessment,” J. Clean. Prod., vol. 368, p. 133033, 2022, doi: 10.1016/j.jclepro.2022.133033.

Y. Hu et al., “Catalytic stepwise pyrolysis for dechlorination and chemical recycling of PVC-containing mixed plastic wastes: Influence of temperature, heating rate, and catalyst,” Sci. Total Environ., vol. 908, p. 168344, 2024, doi: 10.1016/j.scitotenv.2023.168344.

R. Potnuri, C. S. Rao, D. V. Surya, V. Sridevi, and A. Kulkarni, “Two-step synthesis of biochar using torrefaction and microwave-assisted pyrolysis: Understanding the effects of torrefaction temperature and catalyst loading,” J. Anal. Appl. Pyrolysis, vol. 175, p. 106191, 2023, doi: 10.1016/j.jaap.2023.106191.

P. Xue et al., “Mechanism study on pyrolysis interaction between cellulose, hemicellulose, and lignin based on photoionization time-of-flight mass spectrometer (PI-TOF-MS) analysis,” Fuel, vol. 338, p. 127276, 2023, doi: 10.1016/j.fuel.2022.127276.

Q. Lu et al., “A novel interaction mechanism in lignin pyrolysis: Phenolics-assisted hydrogen transfer for the decomposition of the β-O-4 linkage,” Combust. Flame, vol. 225, pp. 395–405, 2021, doi: 10.1016/j.combustflame.2020.11.011.

T. Xie et al., “Co-pyrolysis of biomass and polyethylene: Mechanistic insights into functional group transformations on solid matrix,” Chem. Eng. J., vol. 482, p. 149166, 2024, doi: 10.1016/j.cej.2024.149166.

Y. Jaafar, L. Abdelouahed, A. El Samrani, R. El Hage, and B. Taouk, “Co-pyrolysis of plastic polymers and biomass: Effect of beech wood/plastic ratio and temperature on enhanced oil production in a tubular pyrolyzer,” Renew. Energy, vol. 218, p. 119252, 2023, doi: 10.1016/j.renene.2023.119252.

H. Hassan, M. A. Ahmad, N. D. A. Zali, M. Z. Musa, and F. Senusi, “Co-pyrolysis of palm kernel shell and discarded medical bottle for biofuel production: Synergistic effect and product distribution,” Waste Manag. Bull., vol. 1, pp. 182–194, 2024, doi: 10.1016/j.wmb.2023.11.001.

Q. Van Nguyen, Y. S. Choi, Y. W. Jeong, S. Y. Han, and S. K. Choi, “Catalytic co-pyrolysis of coffee-grounds and waste polystyrene foam by calcium oxide in bubbling fluidized bed reactor,” Renew. Energy, vol. 224, p. 120124, 2024, doi: 10.1016/j.renene.2024.120124.

X. You et al., “Preparation of pyrolyzed CaO-containing carbon pellets: Effect of temperature on pyrolysis behavior and structural evolution,” J. Anal. Appl. Pyrolysis, vol. 168, p. 105740, 2022, doi: 10.1016/j.jaap.2022.105740.

A. Ahmed, S. R. Khan, and M. Zeeshan, “Application of low-cost natural zeolite catalyst to enhance monoaromatics yield in co-pyrolysis of wheat straw and waste tire,” J. Energy Inst., vol. 105, pp. 367–375, 2022, doi: 10.1016/j.joei.2022.10.014.

D. Muniyappan, A. O. P. Junior, A. V. M, and A. Ramanathan, “Synergistic recovery of renewable hydrocarbon resources via microwave co-pyrolysis of biomass residue and plastic waste over spent toner catalyst towards sustainable solid waste management,” Energy, vol. 278, p. 127652, 2023, doi: 10.1016/j.energy.2023.127652.

S.-S. Hou, W.-C. Huang, F. M. Rizal, and T.-H. Lin, “Co-Firing of Fast Pyrolysis Bio-Oil and Heavy Fuel Oil in a 300-kWth Furnace,” Appl. Sci., vol. 6, p. 326, 2016, doi: 10.3390/app6110326.

L. Utarina, Rusdianasari, and L. Kalsum, “Characterization of Palm Shell-Derived Bio-Oil Through Pyrolysis,” J. Appl. Agric. Sci. Technol., vol. 6, pp. 139–148, 2022, doi: 10.55043/jaast.v6i2.69.

S. H. Chang, “Plastic waste as pyrolysis feedstock for plastic oil production: A review,” Sci. Total Environ., vol. 877, p. 162719, 2023, doi: 10.1016/j.scitotenv.2023.162719.

M. Afraz et al., “Production of value added products from biomass waste by pyrolysis: An updated review,” Waste Manag. Bull., vol. 1, pp. 30–40, 2024, doi: 10.1016/j.wmb.2023.08.004.

S. A. Channiwala and P. P. Parikh, “A unified correlation for estimating HHV of solid, liquid and gaseous fuels,” Fuel, vol. 81, pp. 1051–1063, 2002, doi: 10.1016/S0016-2361(01)00131-4.

A. Khan, N. Iqbal, T. Noor, M. Hassan, and J. Akhter, “Synergistic production of fuels from co-pyrolysis of lignite coal and waste plastic,” J. Energy Inst., vol. 113, p. 101527, 2024, doi: 10.1016/j.joei.2024.101527.

M. M. Rahman, M. Chai, M. Sarker, Nishu, and R. Liu, “Catalytic pyrolysis of pinewood over ZSM-5 and CaO for aromatic hydrocarbon: Analytical Py-GC/MS study,” J. Energy Inst., vol. 93, pp. 425–435, 2020, doi: 10.1016/j.joei.2019.01.014.

M. W. Nolte and B. H. Shanks, “A Perspective on Catalytic Strategies for Deoxygenation in Biomass Pyrolysis,” Energy Technol., vol. 4, pp. 1–13, 2016, doi: 10.1002/ente.201600096.

S. R. Khan and M. Zeeshan, “Catalytic potential of low-cost natural zeolite and influence of various pretreatments of biomass on pyro-oil up-gradation during co-pyrolysis with scrap rubber tires,” Energy, vol. 238, p. 121820, 2022, doi: 10.1016/j.energy.2021.121820.




DOI: https://doi.org/10.18196/jmpm.v8i2.22053

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